Journal Articles Submitted or in Preparation

50.  Natasha F. O'Rourke, Michael Ronaldson, T. Stanley Cameron, Ruiyao Wang, Manuel A.S. Aquino, "Equatorial  π-π  Interactions and Hydrogen-bonding in Diruthenium(II,III) Tetracarboxylate Complexes Containing Extended  π-Systems", Inorg. Chim. Acta, submitted for publication.

49.  Karel G. von Eschwege, Lydia van As, Jannie C. Swarts, Manuel A.S. Aquino and T. Stanley Cameron, "Synthesis, Structure and Electrochemical Characterisation of a Novel Cobalt(III) tris-Dithizonato Complex",  Electrochimica Acta, submitted for publication.


Refereed Journal Articles

48.  Luc J. Boudreau, Terri L. Clarke, Adrian H. Murray, Katherine N. Robertson, T. Stanley Cameron, and Manuel A.S. Aquino, "Sterically-Directed Disassembly of Diruthenium(II,III) Tetraacetate using Substituted and Unsubstituted 2,2'-Bipyridines and 1,10-Phenanthrolines", Inorg. Chim. Acta, 2013, 394, 152-158.

47.  Karel G. Von Eschwege, Jannie C. Swarts, Manuel A.S. Aquino and T. Stanley Cameron, "(1,5-Diphenylthiocarbazonato-κ S)trimethyltin(IV)", Acta Cryst., 2012, E68, m1518.

46.  Ramesh Vadavi, Eamonn D. Conrad, D. Ian Arbuckle, T. Stanley Cameron, Ernest Essoun, and Manuel A.S. Aquino, "Chiral Induction via the Disassembly of Diruthenium(II,III) Tetraacetate by Chiral Diphosphines", Inorg. Chem. , 2011, 50, 11862-11864.

45.  Samuel A. Minaker, Ruiyao Wang, and Manuel A.S. Aquino, "Tetra- -acetato- κ8O:O'-bis[3-cyanopyridine- κN1)ruthenium(II,III)](Ru-Ru)hexafluoridophosphate 1,2-dichloroethane monosolvate", Acta Cryst., 2011, E67, m1554.

44.  Henno J. Gericke, Nicola I. Barnard, Elizabeth Erasmus, Jannie C. Swarts, Michael J. Cook and Manuel A.S. Aquino, “Solvent and Electrolyte Effects in Enhancing the Identification of Intramolecular Electronic Communication in a Multi Redox-Active Diruthenium Tetraferrocenoate Complex, a Triple-Sandwiched Dicadmium Phthalocyanine and a Ruthenocene-Containing β-Diketone”, Inorg. Chim. Acta, 2010, 363, 2222-2232.

43.  Michael Ronaldson, Chad R. Maheux, James M. Nyangulu, T. Stanley Cameron and Manuel A.S. Aquino, “12-Ethoxy-2,3,8,9-tetramethyl-benzo-[c]-phenanthradine”, Acta Cryst., 2010, E66, o124.        

42.  Adrian H. Murray, Zhang Yue, Andrew I. Wallbank, T. Stanley Cameron, Ramesh Vadavi, Brian J. MacLean and Manuel A.S. Aquino, "Synthesis, Structure and Electrochemistry of Mononuclear and Dinuclear Ruthenium-Thiophenecarboxylate Derivatives", Polyhedron, 2008, 27, 1270-1279.

41.  Tara J. Burchell, T. Stanley Cameron, Donal H. Macartney, Laurence K. Thompson, and Manuel A.S. Aquino, "Kinetics and Magnetism of Phosphane Diadducts of Diruthenium(II,III) Tetraacetate", Eur. J. Inorg. Chem., 2007, 4021-4027.

40.  Andrew P. White, Katherine N. Robertson, T. Stanley Cameron, Bernard V. Liengme, Daniel B. Leznoff, Simon Trudel, and Manuel A.S. Aquino, "Synthesis and Characterization of [M(DMSO)6][SnCl6] Complexes (M = Fe2+, Co2+ and Ni2+): An Old Mystery Solved", Can. J. Chem., 2007, 85, 372-378.

39.  David Wolstenholme, Manuel A.S. Aquino, T. Stanley Cameron, Joseph D. Ferrara, and Katherine N. Robertson "A Topological Analysis of the Inter-Ion Interactions of Tetraphenylphosphonium Squarate", Can. J. Chem., 2006, 84, 804-811.

38.  Ian W. Wyman, Katherine N. Robertson, T. Stanley Cameron, Jannie C. Swarts, and Manuel A.S. Aquino, "Synthesis, Structure and Electrochemistry of (Ferrocene-2-propenoato-O,O')bis[1,2-bis(di-phenylphosphino)ethane-P,P']ruthenium(II) Hexafluorophosphate", Inorg. Chim. Acta, 2006, 359, 3092-3096.

37.  Ian W. Wyman, Katherine N. Robertson, T. Stanley Cameron, Jannie C. Swarts, and Manuel A.S. Aquino, "Synthesis and Characterization of a Ruthenocenecarboxylate-Containing Ru(II) Complex", Organometallics, 2005, 24, 6055-6058.

36.  Brendan R.A. Bland, Heather J. Gilfoy, Katherine N. Roberston, T. Stanley Cameron, George Vanvounis and Manuel A.S. Aquino, "Hydrogen-Bonding in Diruthenium Tetraacetate Complexes with Biologically Relevent Axial Donors", Inorg. Chim. Acta, 2005, 358, 3927-3936.

35. Jeanet Conradie, T. Stanley Cameron, Manuel A.S. Aquino, Gert J. Lamprecht and Jannie C. Swarts, "Synthetic, Electrochemical and Structural Aspects of a Series of Ferrocene-Containing Dicarbonyl Betadiketonato Rhodium(I) Complexes", Inorg. Chim. Acta,  2005, 358, 2530-2542.

34. Ian W. Wyman, Tara J. Burchell, Katherine N. Robertson, T. Stanley Cameron, and Manuel A.S. Aquino, "Synthesis and Electrochemistry of Heterobimetallic Ferrocenecarboxylatoruthenium(II) Complexes", Organometallics, 2004, 23, 5353-5364.

33. Manuel A.S. Aquino, "Recent Developments in the Synthesis and Properties of Diruthenium Tetracarboxylates", Coord. Chem. Rev., 2004, 248, 1025-1045.

32. Manuel A.S. Aquino and Ian Wyman, "Complexes Containing Metallocene Carboxylate Ligands", Trends in Inorganic Chemistry, 2004, 8, 1-21.

31. Michael W. Cooke, T. Stanley Cameron, Katherine N. Robertson, Jannie C. Swarts and Manuel A.S. Aquino, "Structure and Electrochemistry of Various Diruthenium(II,III) Tetrametallocenecarboxylates", Organometallics, 2002, 21, 5962-5971.

30. Mark B. Twitchett, Gerhard Schenk, Manuel A.S. Aquino, Douglas T.-Y. Yiu, Tai-Chu Lau and A.Geoffrey Sykes, "Reactivity of MII Metal-Substituted Derivatives of Pig Purple Acid Phosphatase (Uteroferrin) with Phosphates", Inorg. Chem., 2002, 41, 5787-5794.

29. Michael W. Cooke, Heather J. Gilfoy, Christopher A. Murphy, T. Stanley Cameron, Ellen J. Beck, George Vamvounis and Manuel A.S. Aquino, "Synthesis and Crystal Structures of Urea and Thiourea Derivatives of Diruthenium(II,III) Tetraacetate", Polyhedron, 2002, 21, 1235-1244.

28. Constance E.J. van Rensburg, Elke Kreft, Sean R. Dalrymple, Denise M. MacDonald, Michael W. Cooke, Jannie C. Swarts and Manuel A.S. Aquino, "Cytotoxicity of a Series of Water-Soluble Mixed-Valent Diruthenium Tetracarboxylates", Anticancer Res., 2002, 22, 889-892.

27. Heather J. Gilfoy, Katherine N. Robertson, T. Stanley Cameron and Manuel A.S. Aquino,  "Synthesis and Structure of the First Sulphur-Donor Adduct of a Diruthenium Tetracarboxylate", Inorg. Chim. Acta., 2002, 331, 330-335.

26. Heather J. Gilfoy, Katherine N. Robertson, T. Stanley Cameron and Manuel A.S. Aquino, "Tetra- -acetato-O:O'-bis(quinoline-N)diruthenium(II,III) hexafluorophosphate quinoline solvate", Acta Cryst., 2001, E57, m496-m497.

25. Glen G. Briand, Michael W. Cooke, T. Stanley Cameron, Heather M. Farrell, Tara J. Burchell and Manuel A.S. Aquino, "An Axial Phosphine Diadduct of Diruthenium(II,III) Tetraacetate", Inorg. Chem., 2001, 40, 3267-3268.

24. Michael W. Cooke, Christopher A. Murphy, T. Stanley Cameron, Jannie C. Swarts and Manuel A.S. Aquino, "Structure and Electrochemistry of Diruthenium (II,III) Tetraferrocenecarboxylate: Evidence for Ferrocenyl-Ferrocenyl Communication", Inorg. Chem. Commun., 2000, 3, 721-725.

23. Christopher A. Murphy, T. Stanley Cameron, Michael W. Cooke and Manuel A.S. Aquino, "Synthesis and Structure of trans-Dimethylammonium Bis(oxalato)diaquaruthenate(III) Tetrahydrate", Inorg. Chim. Acta, 2000, 305, 225-229.

22. George Vamvounis, Jennifer F. Caplan, T. Stanley Cameron, Katherine N. Robertson and Manuel A.S. Aquino, "Synthesis, Structure and Electrochemistry of Nitrogen Base Adducts of Tetraacetatodiruthenium (II,III): Dependence of Redox Potential and Ru-Ru Bond Length on Axial Ligand Donor Strength", Inorg. Chim. Acta, 2000, 304, 87-98.

21. W.C. (Ina) du Plessis, Johannes J.C. Erasmus, Gert J. Lamprecht, Jeanet Conradie, T. Stanley Cameron, Manuel A.S. Aquino and Jannie C. Swarts, "Cyclic Voltammetry of Ferrocene-Containing  -Diketones as a Tool to Obtain Group Electronegativities.  The Structure of 3-Ferrocenoyl-2-Hydroxy-1,1,1-Trifluoroprop-2-ene", Can. J. Chem., 1999, 77, 378-386.

20. Jennifer F. Caplan, Christopher A. Murphy, Susan Swansburg, Robert P. Lemieux, T. Stanley Cameron and Manuel A.S. Aquino, "Evidence of Room Temperature Mesomorphism in a Mixed-Valent Diruthenium(II,III) Quinta-palmitoleate Polymer", Can. J. Chem., 1998, 76, 1520-1523.

19. Ellen J. Beck, Krista D. Drysdale, Laurence K. Thompson, Licun Li, Christopher A. Murphy and Manuel A.S. Aquino, "Weak Intermolecular Antiferromagnetic Exchange in {[Ru2(O2CCH3)4(L)]X}n Polymers (L = 4,4'-Dipyridine and 1,4-Diazabicyclooctane, X = PF6- or BPh4-)", Inorg. Chim. Acta., 1998, 279, 121-125.

18. Manuel A.S. Aquino, "Diruthenium and Diosmium Tetracarboxylates: Synthesis, Physical Properties and Applications", Coord. Chem. Rev., 1998, 170, 141-202.

17. Krista D. Drysdale, Ellen J. Beck, T. Stanley Cameron, Kathy N. Robertson and Manuel A.S. Aquino, "Crystal Structures and Physico-Chemical Properties of a Series of Mixed-Valent [Ru2(O2CCH3)4L2](PF6) Adducts (L = H2O, DMF, DMSO)", Inorg. Chim. Acta, 1997, 256, 243-252.

16. Manuel A.S. Aquino, Christopher A. White, Corinne Bensimon, J.E. Greedan and Robert J. Crutchley, "A Pentaammineruthenium(III) Dimer with the Novel Bridging Ligand 4,4'-Dicyanamidobiphenyl Dianion", Can. J. Chem., 1996, 74, 2201-2208.

15. Joo-Sang Lim, Manuel A.S. Aquino and A. Geoffrey Sykes, "Mechanistic Studies on the Reactions of Mo(VI), W(VI), V(V) and As(V) Tetraoxo-Anions with the Fe(II)Fe(III) form of Purple Acid Phosphatase from Porcine Uteri (Uteroferrin)", Inorg. Chem., 1996, 35, 614-618.

14. Manuel A.S. Aquino, Joo-Yeon Han, Jannie C. Swarts and A.Geoffrey Sykes, "Mechanistic Studies on the Binuclear Fe Enzymes Ribonucleotide Reductase and Purple Acid Phosphatase", D.P Kessissogiou (Ed.), in Bioinorganic Chemistry, Kluwer Academic Publishers, Holland, 1995, 57-65.

13. Manuel A.S. Aquino, William Clegg, Qiu-Tian Liu and A. Geoffrey Sykes, "Structure of Hexaaquatitanium(III) p-Toluenesulfonate Trihydrate",  Acta Crystallogr., Sect. C., 1995, 51, 560-562.

12. Jannie C. Swarts, Manuel A.S. Aquino, Joo-Yeon Han, Kin-Yu Lam and A. Geoffrey Sykes, "Kinetic Studies on the Reduction of the Tyrosyl Radical of the R2 Subunit of E. coli Ribonucleotide Reductase", Biochim. Biophys. Acta, 1995, 1247, 215-224.

11. Manuel A.S. Aquino and A. Geoffrey Sykes, "Redox Reactivity of the Binuclear Iron Active Site of Porcine Purple Acid Phosphatase (Uteroferrin)", J. Chem. Soc., Dalton Trans., 1994, 683-687.

10. Manuel A.S. Aquino, Joo-Sang Lim and A. Geoffrey Sykes, "Mechanism of the Reaction of Different Phosphates with the Fe(II)Fe(III) form of Purple Acid Phosphatase from the Porcine Uterus (Uteroferrin)", J. Chem. Soc., Dalton Trans., 1994, 429-436.

9. Manuel A.S. Aquino, Robert J. Crutchley, Florence L. Lee, Eric J. Gabe and Corinne Bensimon, "Crystal Structures of 1,4-Dicyanomidobenzene Dianion Derivatives", Acta Crystallogr., Sect. C., 1993, 49, 1543-1547.
   
8. Manuel A.S. Aquino, Joo-Sang Lim and A. Geoffrey Sykes, "Mechanism of the Reaction of Phosphate with Purple Acid Phosphatase", J. Chem. Soc., Dalton Trans., 1992, 2135-2136.

7. Manuel A.S. Aquino, Florence L. Lee, Eric J. Gabe, Corinne Bensimon, John E. Greedan and Robert J. Crutchley, "Superexchange Metal-Metal Coupling in Dinuclear Pentaammineruthenium Complexes Incorporating a 1,4-Dicyanamidobenzene Dianion Bridging Ligand", J. Am. Chem. Soc., 1992, 114, 5130-5140.

6. Manuel A.S. Aquino, Florence L. Lee, Eric J. Gabe, John E. Greedan and Robert J. Crutchley, "Long-Range Antiferromagnetic Coupling Between Two Ruthenium(III) Ions Bridged by a 1,4-Dicyanamidobenzene Dianion Ligand", Inorg. Chem., 1991, 30, 3234-3236.

5. Robert J. Crutchley, Akila A. Saleh, Kierstan McCaw and Manuel A.S. Aquino, "Dependence of Ligand to Metal Charge-Transfer Oscillator Strength on the Nature of the Ruthenium(III)-Cyanamide Bond", Mol. Cryst. Liq. Cryst., 1991, 194, 93-101.

4. Manuel A.S Aquino, Ann E. Bostock and Robert J. Crutchley, "A Pentaammineruthenium Mixed-Valence Complex with 1,4-Dicyanamido-2,3,5,6-tetrachlorobenzene Dianion as Bridging Ligand", Inorg. Chem., 1990, 29, 3641-3644.
       
3. Manuel A.S. Aquino, Daniel A. Foucher and Donal H. Macartney, "Electron-Exchange and Electron-Transfer Reactions Involving the Dirhodium(II) Tetraacetate Couple in Acetonitrile", Inorg. Chem., 1989, 28, 3357-3361.

2. Manuel A.S. Aquino and Donal H. Macartney, "Ligand Substitution Reactions of Dirhodium(II) Tetraacetate with Water-Soluble Phosphines", Inorg. Chem., 1988, 27, 2868-2872.

1. Manuel A.S. Aquino and Donal H. Macartney, "Axial-Ligand Substitution Reactions of Dirhodium(II) Tetraacetate with Phosphines and Phosphites in Acetonitrile", Inorg. Chem., 1987, 26, 2696-2700.