Assignment 12 (self-evaluation)

 

Chapter 25     Organic chemistry

 

 

1. Write down examples of the most typical reactions for the following classes of organic compounds:

 

a)      Alkanes (p.1073)

 

C2H6 (g)   +  

 

 

b)      Alkenes and Alkynes (p. 1077)

 

C2H4 (g)   +

 

cyclopentene +

 

C2H4 (g)   +

 

c)      Aromatic hydrocarbons (p.1081)

 

C6H6   +

 

 

 

2. Draw the structures of the following organic compounds:

 

a)      2-butanol

 

 

b)      cis-2-hexene

 

 

c)      para-dinitrobenzene

 

 

d)      2-methyl-1-butene

 

 

 

e)      4,5-dimethyl-2-pentyne

 

 

 

 

 

 

3. Name the following organic compounds

 

 

 

 

 

 

 

 

4. Functional groups     (p.1071,1094)

Circle and name the functional groups which present in the following organic compounds:

 

 

 

 

Answers

 

1. Write down the most typical reactions for the following classes of organic compounds:

 

a)      Alkanes (p.1073)

combustion reactions

 

2C2H6 (g)   +  7O2 (g) à  4CO2 (g)   +  6 H2O (g)

 

 

b)      Alkenes and Alkynes (p. 1077)

 

addition, for example, Cl2

 

C2H4 (g)   + Cl2 (g)  à   H2ClC-CClH2

 

for cyclic alkenes also addition, for example, of  H2:

 

 

 

C2H2 (g)   + Cl2 (g) à HClC=CClH     cis- and trans-1,2-dichloroethene

 

 

c)      Aromatic hydrocarbons (p.1081)

 

substitution

 

C6H6   +  HNO3 à  C6H5NO2       +    H2O

 

                                 (nitrobenzene)

 

 

 

 

 

 

 

 

 

2.

 

 

2-butanol         

 

 

 

cis-2-hexene        

 

 

para-dinitrobenzene         

 

 

2-methyl-1-butene   

 

 

 

4,4-dimethyl-2-hexyne 

 

 

3.

 

 

4. Functional groups

 

 

 

                    

 

From left to right

 

top structure: alkene, alkyne, alcohol

middle structure: aldehyde, amine, ketone, carboxylic acid

bottom structure: amide, ether, ester